NOx generation in marine dual-fuel engines: Effects of ammonia blending ratio and spark ignition timing

Abstract

Ammonia application in marine engines can effectively mitigate greenhouse gas emissions. However, engines powered by ammonia produce considerably higher levels of NOx emissions compared to conventional fuel engines. A combustion model for the marine dual-fuel engine fueled with natural gas and ammonia has been established using the CONVERGE software. The nitrogen element-tracking method is employed in the engine combustion simulation. This study aims to investigate the effects of ammonia blending ratio (XNH3 = 0% ∼ 50%) and spark ignition timing (SIT = -20 °CA ATDC ∼ -40°CA ATDC) on the emission characteristics and spatiotemporal distribution of nitrogen-based pollutants under lean-burn and stoichiometric-burn conditions. The results indicate that as the XNH3 increases, total NOx emissions decrease at stoichiometric-burn conditions, while it initially increases and then decreases at lean-burn conditions, reaching a peak of 3760 ppm at XNH3 = 30%. Besides, fuel NO emissions are predominant at lean-burn conditions, whereas at stoichiometric-burn conditions, thermal N*O emissions are predominant. Additionally, as the SIT advances, total NOx emissions initially decrease and then remain unchanged, reaching a minimum at -35 °CA ATDC, and it gradually increases at lean-burn combustions. Furthermore, the spatial distribution of NO at CA50 illustrates that fuel NO is primarily concentrated at the flame front, while thermal N*O predominates in the high-temperature burned region. N2O is observed in the low-temperature region near the cylinder wall during the expansion stroke. Moreover, fuel NO is primarily produced by ammonia's decomposition with OH radicals. There are three dominant reactions for the formation of NO: HNO→NO, NH→NO, and N→NO. The coupling mechanism of carbon and nitrogen elements is achieved by H2CN and HCN radicals.