Novel technique for fabrication of electrospun membranes with high hydrophobicity retention

Abstract

In a bid to mitigate the problem of pore wetting in membrane distillation, a superhydrophobic membrane was prepared by in situ deposition of teflon oligomer microparticles on poly (vinylidenefluoride-co-hexafluoropropylene) nanofibers during electrospinning. This new approach relies on dusting in the chamber where the threads of polymer solution are spun in the zone of fiber transition between liquid to solid. In addition to distributing the particles across the electrospun mat, the novel technique allows bonding of the particles to the solidified fibers. The prepared membrane was characterized and tested in direct contact membrane distillation (DCMD). The results show that the membrane, which was about 30 μm thick, was superhydrophobic and displayed a water contact angle of 155 ± 1°. The membrane also supported a contact angle of 153 ± 1° for a 3 mM SDS solution having lower surface tension (49 mN/m) than water (72 mN/m). The membrane had nominal and maximum pore diameters of 0.57 μm and 1.93 μm respectively, and was about 91% porous. The membrane also supported a liquid entry pressure of about 22 psi. Furthermore, the membrane gave average permeate fluxes of 7 kg m−2 h−1, 10 kg m−2 h−1 when tested in DCMD at 60 °C and 70 °C feed temperatures respectively, with a salt rejection of 99.97%. Finally, the membrane supported a water contact angle of 140 ± 1° after it had been used in DCMD test, while the mean pore diameter, maximum pore diameter and porosity decreased to 0.32 μm, 0.83 μm and 86.5% respectively after test.