Abstract
The Mn(III)-based reaction of 1,1-disubstituted alkenes with 2-(2-oxoethyl)malonates and 3-acetylpentane-1,4-diones gave novel substituted dihydropyrans and 2,8-dioxabicyclo[3.3.0]oct-3-enes in good yields, respectively. These routes rely on the nucleophilic character of the carbonyl-oxygen atoms of the malonates and pentanediones used to obtain the products by a cycloaddition reaction or cycloaddition–tandem cyclization reactions.
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