Abstract
New types of di-iminonaphthalene-type near-1R dyes have been conveniently synthesized by the condensation of 1 -naphthylcyanamide with p-(N, N-dialkylamino)anilines in the presence of an oxidizing agent. The dyes show λmax 686–779 nm in chloroform, the absorption properties of which are discussed in detail. An intramolecular ring-closure reaction of the acetylamino analogue, N-(2′-acetyl-amino-4′-diethylaminophenyl)-N′-cyano-1,4-naphthoquinone di-imine, under alkaline conditions gave a new benzophenazine dye.
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More From: Journal of the Chemical Society, Perkin Transactions 1
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