Novel spherical InVO4/floral Bi2MoO6 Z-scheme heterojunction for efficient photocatalytic carbon dioxide reduction

Abstract

The development of efficient CO2 reduction photocatalysts is of great significance to improving the global greenhouse effect and alleviating the energy crisis. In this paper, spherical InVO4/floral Bi2MoO6 (IVO/BMO) Z-scheme heterojunction was prepared by a hydrothermal method, and the surface structure, chemical composition, and photovoltaic properties of the samples were characterized and tested for their CO2 reduction performance. The experimental results show that 1.5 %-IVO/BMO exhibits excellent photocatalytic activity for CO2 reduction under the irradiation of 300 W Xenon lamp, with a CO yield of 34.08 µmol/g/h and a CH4 yield of 4.49 µmol/g/h, which are 2.55 and 1.05 times higher than that of the pure Bi2MoO6, respectively. The enhanced photocatalytic activity can be attributed to the formation of an IVO/BMO Z-scheme heterojunction, which promotes electron separation and reduces charge recombination at the interface, facilitating the reaction process. This study provides a novel Z-scheme photocatalyst for efficient carbon dioxide reduction.