Novel solar-induced wastewater purification materials originated from ore tailing solid waste

Abstract

Ore tailings (OT) are solid waste produced as a by-product of the mining industry, posing serious environmental challenges. Ensuring the low-carbon and environmentally friendly development of mineral raw materials, enhancing the reclamation, reuse and recycling rate of raw materials in the full lifecycle, presents a significant challenge. To achieve high-value utilization of OT and solve the problem of clean water supply, a novel solar evaporation wastewater purification material was developed using modified ore tailing/acrylate composite photothermal coating. The photothermal functional modified ore tailings (OT@PDA@CB) were fabricated by grafting carbon black (CB) and polydopamine (PDA) onto the OT surface through the physical adhesion of active chemical groups, synergistically enhancing broadband light absorption ability of OT@PDA@CB/acrylate coating. UV–Vis-NIR spectra showed increased absorption in visible and near-infrared (NIR) light. Surface temperature of OT@PDA@CB/acrylate coating under 1200 W/m−2 illumination increased to 65.6 °C compared with 52.6 °C of OT/acrylate coating due to increased light absorption, resulting in an evaporation rate of 0.89 kg·m−2·h−1 within 1 h. The solar evaporation efficiency for OT@PDA@CB evaporator was 48.3%, which was 192.7% higher than that in blank acrylate sample. The obtained OT@PDA@CB/acrylate composite photothermal coating demonstrated versatile abilities for desalination, heavy-metal purification and organic contaminant removal. This work offers a straightforward approach for high-value utilization of inexpensive mineral solid wastes and green solar-induced wastewater purification technique.