Novel Biomimic Crystalline Colloidal Array for Fast Detection of Trace Parathion.

Abstract

A novel gold doped inverse opal photonic crystal (IO PC) was successfully fabricated with combination of molecularly imprinted technical for the fast determination of parathion. First, a closest silica array arrangement behaved as the 3D photonic crystal precursors to build the opal photonic crystal (O PC). Second, the parathion-containing polymeric solution with gold nanoparticles was drawn into the 3D array cracks. After polymerization, the well-designed O PC was treated with HF solution for the etching of the silica skeleton. Finally, the template parathion was removed and the Au-MIP IO PCs were obtained. The morphology of SiO2 and Au NPs was characterized by transmission electron microscopy (TEM), and the eluted influence of the IO PCs was monitored by scanning electron microscopy (SEM). The cross-linking effect was well optimized according to the best spectrum signal of parathion. The as-synthesized Au-MIP IO PCs displayed the specificity toward parathion and the selectivity to other competitive pesticide molecules. The response time was only 5 min, and the parathion could be well detected from real water samples. The recoveries were between 95.5% and 101.5%.