Novel approach for tuning micellar characteristics and rheology of a sulfate-free anionic surfactant sodium cocoyl glycinate

Abstract

Amino acid based mild and sulfate-free anionic surfactant, sodium cocoyl glycinate (SCGLY) forms spherical micellar aggregates in water. The mixed micellar characteristics of SCGLY has been studied in the presence of nonionic surfactants like cocamide diethanolamine (CDEA) and lauryl glucoside (LG). The ternary aqueous system of SCGLY/CDEA/LG depicts higher surface activity and stronger aggregation ability compared to corresponding single or binary surfactant systems as revealed by tensiometry. The effect of pH (5.5–6.5) and total surfactant concentration (14–18 wt%) on thickening of SCGLY/CDEA/LG system is studied by rheology measurements. The presence of CDEA/LG amid charged SCGLY head group shrinks the electrostatic repulsion and induces sphere-to-rod micellar transition depicting low or moderate viscosity under as-prepared neutral pH. With alteration in pH, viscosity augmented to a maximum (at pH ~5.8) followed by a viscosity decrease. This is a novel finding for mild sulfate-free SCGLY surfactant solution which otherwise is very hard to thicken. Micellar size and charge is attained by dynamic light scattering, while micellar shapes and aggregation numbers are determined by small-angle neutron scattering (SANS) measurements. Moreover, foaming behavior (foamability and stability) and mildness property (zein solubility) of SCGLY can be optimized as per the necessity in the presence of CDEA and LG. This work might prove to be an innovative approach to tune the micellar characteristics and rheology of amino acid based surfactant formulation which could be extremely beneficial for cost-effective, thickener-free, sulfate-free surfactant systems used in cleansing composition with desired viscosity.