Abstract
This manuscript describes the synthesis and coinage metal complexes of pyridine appended 1,2,3-triazolyl-phosphine [2-{(C6H4N)(C2(PPh2)N3C6H5)}] (1), photophysical studies and their catalytic application. The reactions of 1 with copper salts afforded dimeric complexes [{Cu(μ2-X)}2{2-(C6H4N)(C2(PPh2)N3C6H5)}2] (2, X = Cl; 3, X = Br; and 4, X = I). The crystal structure indicates that the Cu⋯Cu distance in 4 (2.694 Å) is significantly shorter than that in complexes 3 (3.0387 Å) and 2 (3.104 Å), indicating strong cuprophilic interactions which is also supported by NBO calculations, signifying the involvement of 3dz2 orbitals from each Cu atom contributing to the bonding interaction. The fluorescence studies on complexes 2-4 carried out in the solid state showed broad emission bands around 560 nm on excitation at λex = 420 nm. Complex 4 on treatment with two equivalents of 1,10-phenanthroline yielded a mononuclear complex 5 which showed almost complete quenching of fluorescence in the solid state, clearly indicating that the emissive properties of 4 are mainly due to the Cu⋯Cu interaction, along with (M + X)LCT. The reactions of 1 with silver salts led to the isolation of dimeric complexes [{Ag(μ2-X)}2{2-(C6H4N)(C2(PPh2)N3C6H5)}2] (6, X = Cl; 7, X = Br; and 8, X = I) in good yield. The reaction between 1 and [AuCl(SMe2)] yielded [{AuCl}{2-(C6H4N)(C2(PPh2)N3C6H5)}] (9). The molecular structures of 2-5 and 7-9 were confirmed by single crystal X-ray analysis. The complex 4 is found to be an excellent catalyst for C-O coupling under mild conditions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have