Abstract

Conventional Landau theory for ferroelectric phase instability is extended by entities accounting for the violation of thermodynamic equilibrium and the impact of thermal fluctuations. The physical content concerns Ginzburg-Landau type model Hamiltonians assigned to the mean field interaction of macroscopically small and microscopically large lattice cells affected by thermal fluctuations. A special topic derived in a systematic way is long range electroelastic interaction formally given by selfconsistent solution of the polarization and strain fields. Test solution for inhomogeneous strain in a slab is presented within the framework of lattice cell picture.

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