Abstract

Diffuse or nonpoint source (NPS) pollution results in different pollutant concentrations, which depend on river catchments, land use and precipitation events and may vary along a single event. This study aimed to assess NPS pollution loads of organic matter, nutrients, bacteria and heavy metals in four river catchments associated with different types of land use in Southern Brazil. Cluster analysis was used to identify similarities between basins and main component analysis (PCA) to identify the main variables that characterize diffuse pollution in each basin. The use and occupation of the soil were determinant in the formation of the clusters. The basins with rural characteristics formed one group, whereas the basin with urban characteristic generated another group. PCA suggests that changes in the water quality of the catchments in this study can be explained by organic pollutants and farming activities. The Rancho do Amaral catchment, with 55.8% of native forest, displayed the lowest NPS pollution load for all tested parameters. The Alto da Colina catchment, with the largest urban area and largest agricultural land use (50%), showed the highest NPS for all variables in the study, even though it has the smallest area. The differences in pollutant loads can be attributed to the intense degradation processes associated with anthropic activities, such as urbanization, agricultural activity and the discharge of effluents, which are different for each catchment.

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