Nonperturbative analysis of the two-level atom: Applications to multiphoton excitation

Abstract

Selective excitation in an atomic system subjected to a slowly varying external electromagnetic field is studied using a two-level model. Time evolution of the system is found using an approach which is nonperturbative in the field strength. There is no constraint to small values of the applied field, that is, the field (in appropriate energy units) need not be small compared to the difference in energies of the two levels. Rather, we prey upon the fact that the situation of interest to us is where the frequency of the exciting field is small compared to the frequency associated with the level difference. Transition probabilities and resonance conditions are found which circumscribe both the large and small field limits. In the weak field limit the previous results of high-order perturbation theory are readily recovered. For a monochromatic field the characteristic features of resonance excitation at high harmonic number of the applied field are (a) extremely narrow resonance widths and (b) shifts in resonance positions which are strong functions of field intensity. Because of this sensitivity, we are able to demonstrate that when slow temporal evolution of the field amplitude is taken into account (e.g., due to finite pulse duration) the appropriate mean excitation rate is that due to the uncorrelated contribution of many resonances. The results of this analysis are used to estimate excitation rates in a specific atomic system, Cd/sup 12 +/, which are then compared to multiphoton ionization rates. Our calculations suggest that the ionization rate exceeds the excitation rate by several orders of magnitude. 15 refs., 3 figs.