Abstract
Chlorine $K$ x-ray-production cross sections have been measured in single collisions of chlorine ions in low incident charge states with gas targets at MeV energies. The cross sections are nonmonotonic as a function of target atomic number, but they approach monotonicity with increasing projectile energy. To explain these results in terms of $2p\ensuremath{\sigma}\ensuremath{-}2p\ensuremath{\pi}$ transitions in nearly symmetric collisions effectively requires $2p$ vacancy production simultaneous with the promotion of Cl $1s$ electrons.
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