Nonlinear rheology of wormlike micelles.

Abstract

Certain viscoelastic surfactant solutions show unusual nonlinear rheology: In steady shear, the shear stress saturates to a constant value while the first normal stess increases roughly linearly with shear rate over several decades. Here we explain this behavior in terms of the ``reptation-reaction'' model for the dynamics of reversibly breakable, polymerlike micelles. The constitutive equation for this model leads to a flow instability of shear-banding type. The limiting shear stress is predicted to be ${\mathrm{\ensuremath{\sigma}}}^{\mathrm{*}}$=0.67${\mathit{G}}_{0}$ (with ${\mathit{G}}_{0}$ the plateau modulus), in quantitative agreement with experiment.