Nonlinear and adaptive control of NO/NO2 ratio for improving selective catalytic reduction system performance

Abstract

Reducing the NOx emissions from Diesel engines remains as a challenging issue as the emission standards for Diesel engine powered vehicles have become more stringent than ever before. Urea-based selective catalytic reduction (SCR) systems have emerged as a promising technique in addressing this issue. However, the SCR performance in terms of NOx reduction and ammonia slip continues as an ongoing challenge due to the engine exhaust gas temperature variations, Diesel emission characteristics (especially high NO/NO2 ratio), and immature SCR controls. The purpose of this study is to improve the SCR performance by feeding the SCR system with exhaust gas having the desired NO/NO2 ratio. The proposed complete active NO/NO2 ratio control consists of a low-level adaptive NO/NO2 ratio controller and a high-level nonlinear soot mass controller. The low-level controller utilizes the pre-SCR catalysts such as Diesel oxidation catalyst (DOC) to convert part of NO into NO2, while the high-level controller was designed and coordinated with the low-level controller to avoid NO2 reduction through the Diesel particulate filter (DPF). Simulation and experimental results show that the proposed active NO/NO2 ratio control has the potentials of regulating the NO/NO2 ratio to the desired value and thus considerably improving the SCR performance. Simulation results also illustrate that the active NO/NO2 ratio control can enable the SCR system size reduction by a half without a significant sacrifice on the overall tailpipe emission control performance. Such an integrated aftertreatment system control can be instrumental in reducing the cost and improving the performance of SCR systems, especially in low-temperature operations.