Nonequilibrium grand-canonical ensemble built from a physical particle reservoir

Abstract

We introduce a nonequilibrium grand-canonical ensemble defined by considering the stationary state of a driven system of particles put in contact with a particle reservoir. When an additivity assumption holds for the large deviation function of density, a chemical potential of the reservoir can be defined. The grand-canonical distribution then takes a form similar to the equilibrium one. At variance with equilibrium, though, the probability weight is "renormalized" by a contribution coming from the contact, with respect to the canonical probability weight of the isolated system. A formal grand-canonical potential can be introduced in terms of a scaled cumulant generating function, defined as the Legendre-Fenchel transform of the large deviation function of density. The role of the formal Legendre parameter can be played, physically, by the chemical potential of the reservoir when the latter can be defined, or by a potential energy difference applied between the system and the reservoir. Static fluctuation-response relations naturally follow from the large deviation structure. Some of the results are illustrated on two different explicit examples, a gas of noninteracting active particles and a lattice model of interacting particles.