Abstract

Paleontological samples are rare and non-renewable, which makes the study of their chemical or physical characteristics require non-destructive methods. Physical characteristics are routinely studied with non-destructive methods; however, chemical studies tend to require destructive methods unless samples are very small or only the surface compositions are of interest. One potential technique for non-destructive elemental analysis is photon activation analysis (PAA). PAA is a versatile, broad-spectrum, multi-element analysis tool with low sensitivities, capable of analyzing large samples without any alteration, preserving the physical characteristics. Recent work has applied PAA to fossils and their source matrices in an attempt to correlate provenance through trace element analysis. PAA was shown to be non-consumptive and able to identify 20+ elements in samples with sub-ppm sensitivities. From that work, several lessons were learned and the non-destructivity of the technique was better characterized. PAA doesn’t have one standardized methodology, as it varies depending on the sample type. As such, from the lessons learned from the previous research, a standard method of applying PAA non-destructively to paleontological samples has been developed and will be presented in the following paper.

Highlights

  • Important to paleontology are both the chemical and physical pathways of information

  • photon activation analysis (PAA) uses high energy photons as an irradiation source. This gives the technique a large penetrability compared to other techniques, allowing bulk analysis of large samples, 100’s of grams or more, with no special considerations

  • The bulk analysis capabilities are of particular importance for the non‐destructive considerations of paleontology

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Summary

Introduction

Important to paleontology are both the chemical and physical pathways of information. This requirement means samples can’t be ground into a fine powder, which is a common, destructive [4] preparation technique This limits the overall mass that can be analyzed, as well as the bulk analysis capabilities. PAA uses high energy photons as an irradiation source This gives the technique a large penetrability compared to other techniques, allowing bulk analysis of large samples, 100’s of grams or more, with no special considerations. The bulk analysis capabilities are of particular importance for the non‐destructive considerations of paleontology Techniques such as NAA are generally limited to sample sizes of around 0.5 g or less [8], unless destructive sample preparation is employed. When used in conjunction with surface techniques, it has the potential to help study migration mechanisms of elements [9]

Methods
Sample Preparation
Irradiation
Counting
Calculations
Applications
Conclusions

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