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Abstract
The crystal structure of metastable LuFeO3 synthesized by containerless processing has been revealed to be a non-centrosymmetric structure (space group P63cm) by analyzing the high-energy synchrotron-radiation powder-diffraction data using the maximum entropy method (MEM)/Rietveld method. The structural characteristics are found in the FeO5 trigonal bipyramid distorted and tilted from the c-axis, which is cause by the hybridization of atomic orbitals between the O atom constituent of the polyhedron and the neighboring Lu atom. The spontaneous polarization expected from the polar structure is estimated at about 5 µC/cm2.
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