Abstract
Non-isothermal melt crystallization kinetics and subsequent melting behavior for four different grades of ethylene–acrylic acid copolymer and three different grades of ethylene–methyl acrylate–acrylic acid terpolymer was investigated by differential scanning calorimetry technique. The non-isothermal melt crystallization data were analyzed based on the Ozawa and Ziabicki macrokinetic models. The effective energy barriers describing non-isothermal melt crystallization process for these resins were determined based on the differential iso-conversional method of Friedman. The amount of non-crystallizable, intra-molecular defects had substantial effects on the non-isothermal melt crystallization kinetics and subsequent melting behavior.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
