Abstract

The produced mechanical work at tensile drawing is converted into heat almost completely and the polymer temperature rises. The temperature rise at adiabatic drawing for different polymers is 20-100°C. To determine the temperature of PET during neck propagation, micro-particles with pre-determined melt surface were dusted on the sample surface. If particles melted, surface temperature exceeded the particle melt temperature. In addition, the temperature rise was analyzed theoretically. The surface temperature of 140°С of PET film samples was recorded. Equations describing distribution of temperature are derived. The equations are solved for steady neck propagation. The drawing ratio in the neck and the draw stress are the main parameters determining the temperature rise. A new method of measurement of the heat transfer coefficient from the neck temperature profile is developed. When the temperature in the yield zone reaches the glass transition temperature, appear pores, the neck drawing ratio increases, and further temperature rises are observed.

Highlights

  • The produced mechanical work at tensile drawing is converted into heat almost completely and the polymer temperature rises

  • It may be performed at elevated temperatures lower than the glass transition temperature

  • The temperature of the polyethylene terephthalate (PET) film in the neck was measured in room conditions at a drawing rate of 1,000 mm/min as described in the ‘Methods’ section

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Summary

Introduction

The produced mechanical work at tensile drawing is converted into heat almost completely and the polymer temperature rises. The temperature rise at adiabatic drawing for different polymers is 20-100°C. If drawing occurs without application of external heat, the process is called cold drawing. Drawing is often done at room temperature and called a cold drawing. It may be performed at elevated temperatures lower than the glass transition temperature. Eventually it grows in length without further change of depth. Upon the passage of this zone through a region, the material in that region is taken from the state of low stretch to the state of high stretch

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