Abstract

Copper hydroxide (Cu(OH)2) is a quite inexpensive and abundant material, but the literature contains no reports of using it as a stable water oxidation catalyst (WOC). In this study, we report for the first time that Cu(OH)2 material synthesized from a simple copper salt can be used as a WOC with good activity and stability. Under optimal conditions using Cu(OH)2 as the electrocatalyst, a catalytic current density of 0.1 mA/cm2 can be achieved under an applied potential of ∼1.05 V relative to Ag/AgCl at pH 9.2. The slope of the Tafel plot is 78 mV/dec. The Tafel plot indicates that a current density of ∼0.1 mA/cm2 requires an overpotential of 550 mV. The Faradaic efficiency was measured to be ∼95%. The as-synthesized Cu(OH)2 material was characterized by X-ray powder diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy.

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