Abstract
Two analytical methodologies have been devised to treat the NMR sequence data of copolymers that are made at high conversions. The first approach is a computer simulation method whereby the copolymerization is simulated through a Monte Carlo process, and the copolymer sequences obtained are compared with the observed NMR data. In the second approach, the NMR triad data are directly analyzed through the first-order Markovian statistics with provision made for conversion. A simplex algorithm is used to optimize the parameters. The procedure has been automated. Examples are shown to illustrate the use of these approaches.
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More From: International Journal of Polymer Analysis and Characterization
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