Abstract
The reaction of a number of azido sugars with hydrazine has been studied. Vicinal azido-hydroxyl compounds gave the appropriate amino-alcohol, trans (ax-ax) and cis (ax-eq) azido-sulphonates both gave the corresponding olefin; trans (eq-eq) azido-sulphonates gave deoxy-sulphonates in which the HCN 3 group had been reduced to CH 2. Possible mechanisms are discussed.
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