Abstract
Studies have been made of the periodate oxidation of carbohydrate derivatives containing the -CH(OH)-CH(NHMe)- and -CH(OH)-CH(NMe 2)- groupings, and having an eq,eq and ax,ax arrangement in each case. In the dimethylamino system, each compound gave the N-oxide, whereas the methylamino systems followed an oxidation pattern similar to that of the analogous -CH(OH)-CH(NH 2)- system studied in earlier work. Oxidation of compounds containing the -CH(OMe)-CN(NH 2)- grouping occured very slowly in a non-Malapradian fashion.
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