Abstract
A facile method to prepare nitrogen anion-decorated cobalt tungsten disulfides solid solutions, retaining ultra-thin WS2-like nanosheet structures (The N–CoxW1−xS2) anchored on carbon nanofibers (CNFs), is developed. The synergistic effect of the WS2 nanosheets provides a secure framework for stabilizing the amorphous Co–S clusters, CNFs substrate and nitrogen anion-decoration significantly enhances the inherent conductivity of the catalyst, resulting in a significantly promoted hydrogen evolution reaction activity and stable performance compared to pure Co9S8 nanoparticles or ultra-thin WS2 nanosheets. The N–CoxW1−xS2 electrode demonstrates the excellent electrocatalytic performance, with current density of 10 mA cm−2 at a low overpotential of 93 mV and Tafel slope of 85 mV dec−1, as well as the long-term stability in acid electrolyte. The present investigation may provide a feasible strategy for incorporating other heteroatoms into transitional metal disulfides materials to design catalysts with highly active and stable performance for water splitting.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.