Nitrogen admixture-driven electron cooling and plasma bullet dynamics in atmospheric-pressure dc nanosecond-pulsed argon jet plasmas

Abstract

We present experimental measurements of the electron temperature and density profiles and analyze the dynamics of a plasma bullet at volumetric concentrations of nitrogen admixture, 0%–3%, in an atmospheric-pressure nanosecond-pulsed argon jet plasma. Time-resolved Thomson scattering measurements taken 2.5 mm from the exit plane reveal that the temporal maximum of electron temperature and density reduced by as much as 55% and 29%, respectively, when mixing only 3% nitrogen to pure argon. These trends were consistent across axial locations from 2.5 to 14 mm from the exit plane for both electron temperature and density at nitrogen admixture plasmas. Moreover, the propagation velocity and length of the plasma bullet decreased by 13% while the radius by 23% at 3%-nitrogen admixture when compared to the pure argon jet case. The analysis suggests that the nitrogen admixture causes electron cooling due to inelastic energy losses, which results in a reduced electron density and propagation velocity due to a decrease in the electron-impact ionization rate. It is therefore inferred that the electron cooling mechanism and reduced density at nitrogen admixture will significantly impact the electron-impact excitation rate coefficient of nitrogen as well as the concentration of the precursor species such as N2(A3Σu+).