Nine years of research and development on advanced water electrolysis. A review of the research programme of the Commission of the European Communities

Abstract

The development of advanced water electrolysis was one of the main tasks of the R & D programme on hydrogen funded, within its main R & D programme on Energy, by the Commission of the European Communities. Most of the work has been concentrated on the development of alkaline water electrolysis, as this process appears particularly promising. (Water electrolysis based on ‘acidic’ solid polymer electrolytes, developed during the last 10 years, seems to be a potentially attractive alternative technology, at least for electrolysers of smaller scale (up to 100kW). Even at this size, however, there is not yet evidence of any overall economic advantage over advanced alkaline cells.) The results of 9 years of R & D in this field are critically examined, by reviewing the improvements achieved on the components of the electrolytic cell as well as the overall modification of the cell design. The anode, cathode and diaphragm have been the components investigated, but also the constituent materials, the nature of the electrolyte and its operating conditions have been dealt with. Three main lines of advanced electrolyser development were identified in the course of these investigations. The corresponding charcteristics are: In cell design, very compact cell units have been devised, in which a ‘zero gap’ configuration (anode and cathode are placed directly on the diaphragm) is generally adopted, resulting in very low internal cell resistance (about 0.2 Ω cm2). Potential energy savings of 20 to 30% can be anticipated for the advanced electrolysis. In addition to this work on advanced alkaline water electrolysis, some limited research efforts on high temperature (>1100 K) water vapour electrolysis have been made and are reported. The latter work has been concentrated on the production of thin-layer doped zirconia solid electrolytes (d=50μm), potentially leading to high performance cells. The economic implications of high-temperature vapour electrolysis, however, cannot be judged at the present status of development.