Abstract
The application of phase change materials (PCMs) in solar energy is hampered by challenges such as insufficient photothermal conversion efficiency, low thermal conductivity and leakage. In this study, a novel composite PCMs based on NiCo@EG were prepared to solve the problems of low thermal conductivity, high leakage rate and inefficient photothermal performance. The NiCo@EG is obtained through calcination of the product of Ni-Co-BTC in-situ on expanded graphite (EG). In the composite PCMs, the octadecanol (OD) acts as a latent heat storage unit, the EG retains its porous network structure as an encapsulating skeleton. The nickel and cobalt nanoparticles derived from Ni-Co-BTC bimetallic organic frameworks are uniformly fixed on the surface of the EG, which could not only construct multiple thermal conduction pathways, but also enhance the photon-trapping ability. Benefiting from the synergy effect of nickel, cobalt metal nanoparticles and EG, the prepared OD/NiCo@EG-550 composite PCMs display high latent heat (168.3 J/g), excellent photothermal conversion efficiency (98.71 %), and improved thermal conductivity of 12.873 W/(m·K). Furthermore, the composite PCMs demonstrate exceptional shape stability, thermal stability, and robust thermal reliability. In summary, the high-efficiency photothermal composite PCMs display significant potential in improving the utilization of solar energy.
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