Abstract

The first example of the title reaction involving the combination of an aryl aldehyde, norbornene, and silane has been developed (see scheme). The reaction involves aromatic CH bond activation of an aryl aldehyde at the ortho position, it proceeded with good diastereoselectively, and is applicable for various aryl aldehydes and norbornenes or norbornadienes. cod=cycloocta-l,5-diene, THF=tetrahydrofuran, NHC=N-heterocyclic carbene.

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