Abstract

AbstractA versatile three‐component coupling of aldehydes, alkynes and amines has been developed, catalyzed by Ni2+‐exchanged Y‐zeolite, which acts as an environmentally benign, recyclable, efficient and heterogeneous catalyst. This three‐component (A3) coupling (reported for the first time to proceed under nickel catalysis) is carried out under solvent‐free conditions, and the corresponding propargylamines are obtained in good to excellent yields.

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