Abstract
The template reaction of isonitrosoacetylacetone (Hina) witho-phenylenediamine (o-phenen) in the presence of (MeCO2)2Ni·4H2O in EtOH yielded three types of nickel(II) complexes (depending on the molar ratio of the reactants) formulated as L1Ni(O2CMe)·2H2O (1), (L1)2Ni (2), and L2Ni·H2O (3). HL1 and H2L2 are the half unit and symmetric Schiff base ligands obtained from the (1∶1) and (2∶1) condensation of (Hina) with (o-phenen) respectively. The (1∶1) molar ratio reaction of (1) with either acetylacetone (Hacac) or (Hina) in CHCl3 led to the formation of mixed ligand complexes L1Ni(acac)·H2O (4) and L1Ni(ina)·H2O (5) whereas a similar reaction with salicylaldehyde (Hsal) produced L3Ni (6); H2L3 is the unsymmetric Schiff base formed by the (1∶1) condensation of the amino group in (1) with (Hsal). Analytical, spectral and magnetic moment evidence are compatible with the suggested structures of the metal complexes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
