Ni-based plasmonic photocatalysts for solar to energy conversion: A review

Abstract

Plasmonic-based semiconductors are compelling contenders of current research endeavors to drive chemical reactions via plasmonic and phononic light-matter interactions. Among various plasmonic metals, Ni as a non-precious metal has been extensively studied due to its ability to participate in interband excitation and comparable metal-hydrogen binding energy to that of noble metals including Pt and Ag. The phenomenally high charge-carrier density in photoexcited Ni-based plasmonic nanomaterials offers photochemical conversion of high-energy chemical bonds accompanied by thermal effect. Since the research on the plasmonic activity of the non-precious metal is still emerging, no comprehensive review has addressed the significance of Ni as a plasmonic photocatalyst to the best of our knowledge. This review article sums up the recent progress in the field of plasmonic photocatalysis focusing on Ni-based photocatalysts. The basic principles of the plasmonic effect have been presented, along with an explanation of why Ni may be a viable option. Ni has been investigated for use as a co-catalyst and plasmonic photocatalyst in composite photocatalysis to achieve an accelerated process. After the energy transfer mechanism has been assessed, the review covers the state-of-the-art of two significant effects—plasmon energy transfer and the localized heating effect that are responsible for increased efficiency in energy production. In conclusion, we have included a synopsis of the assessment and emphasized the problems that must be resolved before the technology can be made available for purchase. In a nutshell, the chemistry of plasmonic photocatalysis is promising; but acquiring a detailed mechanism of charge transfer and utilization of charge carriers is still a roadblock in apprehending the full potential of plasmonic photocatalysis. Therefore, this study aims to motivate the scientific community to envision impactful work in the creation of next-generation plasmonic photocatalysts.