Abstract
This review describes new reactions catalyzed by recently discovered types of metal complexes and catalytic systems (catalyst + co-catalyst). Works of recent years (mainly 2010–2016) devoted to the oxygenations of saturated, aromatic hydrocarbons and other carbon–hydrogen compounds are surveyed. Both soluble metal complexes and solid metal compounds catalyze such transformations. Molecular oxygen, hydrogen peroxide, alkyl peroxides, and peroxy acids were used in these reactions as oxidants.
Highlights
This review is devoted to functionalization of carbon–hydrogen bonds [1,2,3,4,5,6,7,8,9,10,11,12,13] in various organic
Photohomolysis of the FeIII –Cl bonds leads to the generation of reactive Cl‚ radicals [61] which attack both the alkane and the alcohols used as a solvent with comparable rates
Alkanes are transformed into derivatives which are more reactive in comparison with parent hydrocarbons, and this makes the selectivity one of the most important problems in functionalizations of saturated hydrocarbons as well as aromatic and other carbon–hydrogen compounds
Summary
2016; Accepted: 16 March+2016; Published: date devoted to the oxygenations of saturated, aromatic hydrocarbons and other carbon–hydrogen. Both soluble metal catalyzed complexes soliddiscovered metal compounds catalyze complexes and catalytic systems Hydrogen peroxide, alkyl peroxides, and peroxy acids were the oxygenations of saturated, aromatic hydrocarbons and other carbon–hydrogen useddevoted in theseto reactions as oxidants. Both soluble metal complexes and solid metal compounds catalyze such transformations. Hydrogen peroxide, alkyl peroxides, and peroxy acids were.
Sign-in/Register to view highlights & summary 
Published Version (
Free)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call