Abstract

AbstractHeterocyclic compounds containing two and three adjacent hydrogen bond donor and acceptor sites in all possible arrangements were synthesized (see generalized structures shown below) to study and use their “base‐pairing” capabilities. With two adjacent donor and acceptor groups there are three possible arrangements and these form two types of complexes (DA·AD and AA·DD). Three adjacent hydrogen bond donor and acceptor sites can be arranged in six different ways and these form three different complexes (ADA·DAD, AAD·DDA, and AAA·DDD).

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