Abstract
Spectral hole burning is observed for the OH stretching mode of HDO dissolved in ${\mathrm{D}}_{2}$O at 298 K after intense infrared excitation. Three spectral components are inferred from the transient band shapes and related to an icelike molecular environment and other hydrogen-bonding configurations. A population lifetime of ${\mathit{T}}_{1}$=8\ifmmode\pm\else\textpm\fi{}2 ps and an anharmonic frequency shift of 270\ifmmode\pm\else\textpm\fi{}20 ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$ are measured.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
