Abstract
1-Alkyl-1,2,4-triazoles were quaternized at N-4 in >98% isolated yields using polyfluoroalkyl halides under neat reaction conditions at 100-120 °C to form 1-R-4-R t -triazolium (Taz) halides. Metathesis of these polyfluoroalkylated triazolium halides with fluorine-containing anions led to the formation of new ionic liquids, [R(Rf)Taz] + Y - .
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