Abstract
New data on phase equilibria in binary and ternary mixtures containing (−)-menthol, n-decane, 1-decanol and water are presented and discussed. In particular, experimental liquid-liquid equilibrium phase diagrams in ternary systems {(−)-menthol + (n-decane, or 1-decanol) + water} are reported along with the predictions by means of leading thermodynamic models, namely, perturbed-chain statistical associating fluid theory (PC-SAFT) and conductor-like screening model for real solvents (COSMO-RS). Freezing pressure data for binary systems {(−)-menthol + (n-decane, or 1-decanol)} are reported and the corresponding high-pressure solid-liquid equilibrium phase diagrams are discussed and analyzed by using the Yang equation. The measured data are referred to ambient-pressure phase diagrams published previously.
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