Abstract
New bis(ethylenedithio)tetraselenafulvalene (BETS) based radical cation salts with chloromercurate anions have been prepared by electrocrystallization. The salt (BETS) 4Hg 3Cl 8 is metallic down to 32 K, at lower temperatures the resistance grows smoothly being lower than the starting value. The salt (BETS) 4Hg 2Cl 6(C 2H 5Cl) x , x∼1, undergoes a metal-to-insulator transition near 100 K. The crystal structure of (BETS) 4Hg 3Cl 8 is formed by the layers of the BETS radical cations of the κ-type packing and inorganic layers composed of the [Hg 2Cl 6] 2− anions and the HgCl 2 molecules.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
