Abstract
The yield and stability of fullerenes with carbon cages in the size gap between C 70 and C 84 is strongly dependent on the metals included. It is shown for C 72 and C 74 cages that they can be stabilised by metal ion inclusion. A review is given for new fullerene structures. A number of new endohedral fullerenes were isolated and described in their optical and redox properties. New fullerene structures presented are: La 2 @C 72 , Ce 2 @C 72 , Eu@C 74 , Tm@C 78 , and Sc 3 N@C 80 . The existence of a selected cage size and isomeric cage is discussed with respect to the metal and its redox state.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.