Abstract

Crystal structures of some new compounds have been determined using X-ray powder data. The intermetallic compounds YbZn 1.75Al 2.25, SmZn 1.62Al 2.38, NdZn 2.34Al 1.66 have the BaAl 4-type structure (s.g. I4/ mmm). Other compounds adopt the La 3Al 11-type structure (s.g. Immm): Y 3Zn 3.2Al 7.8, Gd 3Zn 3.4Al 7.6, Tb 3Zn 4.6Al 6.4, Dy 3Zn 3.4Al 7.6, Ho 3Zn 4.4Al 6.6, ∼Er 3Zn 4Al 7, ∼Tm 3Zn 4Al 7.

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