New insights into the interaction between sorbitol-based liquid-type temperature rise inhibitor and cement hydration: From experiments to molecular dynamic simulations

Abstract

The use of temperature rise inhibitors (TRIs) holds significant promise in mitigating thermal cracking issues in modern concrete by controlling the precipitation of C-S-H gel, the main product of cement hydration. However, the complexity of their interaction with the non-classical nucleation process of C-S-H remains unclear. This study systematically investigated the influence of a sorbitol-based liquid-type temperature rise inhibitor (L-TRI) on the hydration kinetics of cement suspension using a combination of methods, including conductivity testing, pore solution analysis, and molecular dynamic simulations. It is revealed that the admixture-to-water ratio, rather than admixture-to-cement ratio, governs the effect of L-TRI on cement hydration. The disturbance of L-TRI molecules in the pore solution, mainly calcium complexation and water stabilization, plays a decisive role in inhibiting the secondary nucleation of C-S-H and decelerating the following growth. In contrast, L-TRI has a negligible influence on cement dissolution and the formation of C-S-H precursor.