Abstract
AbstractThe conjugate Michael addition of methylamine to alkyl acrylates can be performed under mild conditions without a catalyst to obtain new hydrophobic intermediates of aminodiester‐type. The reactants used strictly in 1:2 molar ratio provide almost quantitative yield of aminodiesters without formation of undesired aminoesters and any other by‐products. Aminodiesters can be purified if necessary by classical methods. The alkyl chain length in the acrylates used has no influence on the results.
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