Abstract

The Bayan Obo deposit in the Inner Mongolia, North China Craton, is the largest rare-earth element (REE) resource in the world. The deposit is hosted in Mesoproterozoic sediments of the Bayan Obo Group, the lithological sequence of which has been divided into seventeen units (H1–H17). The REE mineralization is mainly concentrated in the H8 dolomite unit, and therefore the depositional age of this unit is important in addressing the debate over the genesis of the REE–Fe–Nb ore deposit. Here we present U–Pb and Hf model ages of zircons from the adjacent H9 slate. Our data suggest that the H9 slate formed at 1505±12Ma and the H8 dolomite was deposited during the Mesoproterozoic. We also present Ar–Ar ages of riebeckite in veins cutting the H8 dolomite and biotite in the ore bodies which show 389.5±3.0Ma and 289.1±1.8Ma, respectively. The U–Pb measurements from overgrowth zircon in H9 slate give an age of 518.8±7.5Ma. These new age data indicate that the Bayan Obo deposit was disturbed during thermal events at 520Ma to 390Ma, generating a second phase of REE–Nb mineralization. The δ7Li values of the REE mineralized dolomite are similar to those of carbonatite dykes. Combined with ɛNd features, we provide geochemical evidences that REE mineralized dolomite has undergone fluid interaction. Results reveal that the carbonatite magmatism occurred within the Bayan Obo rift at ca. 1.2 Ga, provided the primary source for REE–Nb mineralization or to fertilize the Bayan Obo crust, and the later was remobilized during the Caledonian to generate the second phase of mineralization within a convergent plate margin regime.

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