Insights into the Ore Genesis of the Giant Bayan Obo REE-Nb-Fe Deposit and the Mesoproterozoic Rifting Events in the Northern North China Craton

Abstract

Listen

Translate article

Bayan Obo ore deposit is the largest rare earth element (REE) resource and the second largest niobium (Nb) resource in the world. The REE enrichment mechanism and genesis of this giant deposit still remains intense debated. The deposit is hosted in the massive dolomite, and nearly one hundred carbonatite dykes occur in the vicinity of the deposit. The carbonatite dykes can be divided into three types from early to late: dolomite, coexisting dolomite–calcite, and calcite type, corresponding to different evolutionary stages of carbonatitic magmatism, and the latter always has higher LREE content. The origin of the ore-hosting dolomite at Bayan Obo has been addressed in various models, ranging from a normal sedimentary carbonate rocks to volcano-sedimentary sequence, and a large carbonatitic intrusion. More geochemical evidences and field interspersed relationship show that the coarse-grained dolomite represents a Mesoproterozoic carbonatite pluton and the fine-grained dolomite resulted from the extensive REE mineralization and modification of the former one. The ore bodies, distributed along an E-W striking belt, occur as large lenses and underwent more intense fluoritization and fenitization with wall rocks. The first episode mineralization is characterized by disseminated mineralization in the dolomite. The second or main-episode is banded or massive mineralization, cut by the third episode consisting of aegirine-rich veins. Various dating methods gave different mineralization ages at Bayan Obo, resulting in long and hot debates. Compilation of available data suggests that the mineralization is rather variable with two peaks at ~1400 and 440 Ma. The early mineralization peak closes in time to the intrusion of the carbonatite dykes. A significant thermal event at ca. 440 Ma resulted in the formation of late-stage veins with coarse crystals of REE minerals. Fluids involving in the REE-Nb-Fe mineralization at Bayan Obo might be REE-F-CO2-NaCl-H2O system. The presence of REE-carbonates as an abundant solid in the ores shows that the original ore-forming fluids are very rich in REE, and therefore, have the potential to produce economic REE ores at Bayan Obo. The Bayan Obo deposit is a product of mantle-derived carbonatitic magmatism at ca. 1400 Ma, which was likely related to the breakup of the supercontinent Columbia. Some remobilization of REE occurred due to subduction of the Palaeo-Asian oceanic plate in the Early Paleozoic, forming weak vein-like mineralization.