Abstract
Two heterocyclic thiolate ligands, namely pymt and py2S (pymt=pyrimidine2-thiolate and py2S=pyridine-2-thiolate) and the diphosphines bis(diphenylphosphino)methane (dppm), 1,2-bis(diphenylphosphino)ethane (dppe), 1,3-bis(diphenylphosphino)propane (dppp), were used in the synthesis of three neutral Pd(II) complexes (cis-[Pd(dppm)(pymt)2] (1), cis-[Pd(dppe)(pymt)2] (2) and cis-[Pd(dppp)(pyrt)2] (3)). Crystallographic analysis of the isolated complexes reveals their square planar arrangement and the coordination of the thiolate moieties through their exocyclic sulfur atom. The complexes absorb in the visible part of the spectrum through charge transfer transitions while after photoexcitation at 385nm they appear to emit with a broad band located at 465nm.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
