Abstract
Nanoparticle networks have potential applications in brain-like computing yet their ability to adopt different states remains unexplored. In this work, we reveal the dynamics of the attachment of polyelectrolytes onto gold nanoparticles (AuNPs), using a bottom-up two-bead-monomer dissipative particle dynamics (TBM-DPD) model to show the heterogeneity of polymer coverage. We found that the use of one polyelectrolyte homopolymer limits the complexity of the possible engineered nanoparticle networks (ENPNs) that can be built. In addressing this challenge, we first found the commensurability rules between the numbers of AuNPs and poly(allylamine hydrochloride)s (PAHs). This gives rise to a well-defined valency of a AuNP which is the maximum number of PAHs that it can accommodate. We further use an engineered block copolymer, which has a conductive middle block to mediate the distance between a dimer of AuNP. We argue that by controlling the length of conductive block that is connecting the AuNPs and their respective topology, we can have ENPNs potentially adopt multiple states necessary for primitive neuromorphic computing.
Published Version
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