Abstract
Abstract Asymmetric activation of aquo Pd catalysts with tropos biphenylphosphine (BIPHEP) ligands by a chiral diaminobinaphtyl (DABN) activator exhibits a remarkable negative nonlinear effect, (–)-NLE, with higher catalytic efficiency than that achieved by enantiopure atropos BINAP- or tropos BIPHEP-Pd catalysts without DABN activator.
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