Abstract
The metal complex of the chirally flexible biphenylphosphine (BIPHEP) exists as an equilibrium between the enantiomeric pairs due to the flexibility of BIPHEP. The dynamic chirality control of the BIPHEP ligands in enantiomerically pure forms to give diastereomerically pure metal complexes with respect to their Ru(II) complexes by their molecular design with the introduction of a substituent in the chiral diamines rather than in the biphenylphosphine is described.
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