Abstract
The photokinetics of the interaction of aromatic esters with aliphatic amines was studied by stressing in the usual kinetic scheme a first order rate constant k t which accounts for the formation of exciplexes and radical ion pairs via the encounter complex in situations of near diffusion controlled quenching. In contrast with the viscosity dependence of the encounter efficiency γ the values obtained for k t vary with the solvent polarity and with the electronic affinity of the esters in the excited state and the ionization potentials of the aliphatic amines.
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