Abstract
The concentration dependence of the specific conductivity of aluminum chloride, chloroderivatives of aluminum hydride and lithium aluminum hydride in tetrahydrofuran were measured. Two types of the conductivity-concentration curve were obtained; the one is linear and the other is concave upward, which may be due to a disproportionate ionization process and due to a variation in the association number with a change in concentration, respectively. The reaction of aluminum chloride with lithium aluminum hydride is also investigated by the conductivity method. The formation of the species AlHCl 2 and AlH 2Cl and of ionized complex Li +AlHCl 3 − and Li +AlH 2Cl 2 − in tetrahydrofuran is proposed to account for the maxima in the conductivity curves. The formation of the complex in diethyl ether is also briefly discussed.
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